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Why is there an increase in boiling point with larger alkaline molecules?

Why is there an increase in boiling point with larger alkaline molecules?

Why do isomers have different boiling points?


Why is there an increase in boiling point with larger alkaline molecules? – This is because of increased surface area for interaction as well as increased number of interactions between molecules

Why do isomers have different boiling points? – This is because some isomers are linear and others are branched which brings about the difference in the arrangement and interactions between the molecules and strength of the bonds


Why is there an increase in boiling point with larger alkaline molecules?

There are two reasons as to why there is increases in boiling point with larger alkaline molecules:

  1. Increased surface area of a large molecule provides greater possibility for interaction between molecules and this increase the boiling point.
  2. As the alkane chain increases or lengthens, there is an increase in the number of electrons that can interact between molecules as well as an increased molecular mass which results into higher boiling points

Why do isomers have different boiling points?

This is because isomers have different forms of contacts between the molecules. This means that for the branched alkanes which have weaker van der waals forces because of the smaller area of contact between the molecules there is less energy is needed to overcome the intermolecular force and thus having less boiling point that the linear alkanes which can line up more closer and therefore have stronger van der waals forces than unbranched alkanes.

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